Polycyclic aromatic hydrocarbons, or starphenes, are composed of three distinct acene-arm variants. The fundamental building blocks for the downsizing of various electronic devices, particularly organic ones, are starphenes. It was also a key component of several logical gates. Every electrical circuit, structure, or network in network topology can be represented as a graph with line segments (branches) acting as edges and primary nodes (or simply nodes) alternating to vertices. Resolvability parameters of a graph are a relatively recent specialized field in which the unique location of each primary node is obtained by forming the network as a whole. This article investigates the metric, edge metric dimension, and generalizations as resolvability characteristics of starphene structure. We demonstrated the consistent cardinalities of all the parameters examined for the starphene graph. Transforming the entire structure into a fresh shape provided by resolvability parameters facilitates understanding and handling of structures.